In-situ preparation of cross-linked hybrid anion exchange membrane of quaternized poly (styrene-b-isobutylene-b-styrene) covalently bonded with graphene

Introducing graphene into polymer matrix is an effective way to enhance performances of anion exchange membrane (AEM). However, utilizing the advantages of graphene by physical approach is limited due to the weak interface interaction between graphene and polymer matrix. Herein, we report an effective strategy to covalently bond graphene with polymer matrix to improve the interface interaction and further to improve the properties of AEM. A series of cross-linked quaternized graphene-based hybrid AEM were fabricated by covalently bonding poly (vinylbenzyl chloride) grafted graphene (GN-g-PVBC) copolymer with chloromethyl functionalized poly (styrene-b-isobutylene-b-styrene) (SIBS) through the cross-linker (N,N,N′,N′-tetramethyl-1,6-hexanediamine) by in-situ synthetic approach. The interface interaction between graphene and QSIBS is greatly enhanced according to micromorphology characterization of the hybrid membrane. The cross-linked quaternized hybrid AEM containing 0.55 wt% of GN-g-PVBC exhibits obviously improved dynamical mechanical properties (storage modulus: 418 MPa), ion conductivity (1.81 × 10² S cm^?1), methanol barrier property (5.19 × 10^?7 cm² s^?1), selectivity (3.49 × 10⁴ S s cm^?3) at 60 °C and especially a comparably excellent chemical stability to that of Nafion 115 due to the enhanced interface interaction between graphene and the polymer matrix.     

Selection of risk response actions with consideration of secondary risks

Secondary risk in project risk management refers to the risk that arises as a direct result of implementing a risk response action (RRA). It is important for project managers (PMs) to consider the effects caused by the secondary risks in the process of RRA selection. The purpose of this paper is to propose an optimization method to address the problem of selecting risk response actions (RRAs) with consideration of secondary risk which is seldom considered in the existing studies. The optimization model aims to minimize the total risk costs with time constraint being placed on the project makespan. By solving the model, an optimal set of RRAs along with the earliest start time for each activity can both be obtained. The results show that secondary risk plays an important role in the process of RRA selection. Project managers should allocate more budget for responding the project risk when the secondary risk is considered, and consider all factors relating to both time and cost so as to select appropriate RRAs to mitigate primary risk and secondary risk.     

响应面曲线法优化贵州某磷块岩浮选工艺研究

对贵州某沉积钙质磷块岩进行了浮选工艺研究。采用H₂SO₄为氟磷灰石抑制剂、BW-1为白云石捕收剂,进行了浮选单因素试验; 在此基础上进行了正交试验,并采用响应面曲线法进行了浮选条件优化。确定了最佳浮选条件为: 磨矿细度-0.074 mm粒级占60%、H₂SO₄用量13.20 kg/t和BW-1用量400 g/t。采用一段反浮选试验流程,可得到精矿品位30.94%、回收率92.45%的磷精矿。研究结果表明,磨矿细度与H₂SO₄用量的交互作用对精矿品位影响显著,H₂SO₄用量和BW-1用量的交互作用对精矿回收率影响显著。     

腐蚀对模块式钢结构选煤厂设备支架振动响应影响的测试及分析

选煤厂采用模块式钢结构作为设备支架,受设备使用及养护不当造成结构构件严重腐蚀,构件截面削弱,导致结构产生过大振动,通过对结构各层振动响应测试,得到各测点水平向及竖直向振动速度幅值。经分析得出腐蚀后对结构整体刚度影响程度,为后期采取措施及安全生产提供依据。     

Stochastic collocation-based nonlinear analysis of concrete bridges with uncertain parameters

This paper focuses on the stochastic response of concrete bridges considering uncertainty in bearing and abutment stiffness. A multi-span simply supported bridge with concrete girders is selected. A 3D-dimensional model is prepared, and nonlinear response history analyses are performed. For the numerical dynamic simulation, the non-sampling stochastic method based on generalized polynomial chaos (gPC) expansion is utilised. The uncertain parameters include the vertical and shear stiffness of bearings and the lateral stiffness of abutments are presented by the truncated gPC expansions. Furthermore, the system response such as base shear, acceleration, velocity and displacement in different columns is presented by gPC expansion with unknown deterministic coefficients. The stochastic Galerkin projection is employed to calculate a set of deterministic equations. A non-intrusive solution, as a set of collocation points, determines the unknown gPC coefficients of the system response and the results are compared with Monte Carlo simulations. The key advantage of spectral discretization is the combination of the mentioned method with the spatial discretization, e.g. finite element model. This study also emphasises the accuracy in results and time efficiency of the proposed non-sampling method for uncertainty quantification of stochastic systems comparing to sampling procedure (e.g. Monte Carlo simulation).     

航空发动机进气总温传感器测温误差研究

航空发动机进口总温测量的准确性是优化发动机控制率、保障发动机飞行安全的关键因素之一。针对影响传感器测量准确性的响应时间、恢复系数，通过空气动力学和热力学理论，分析出具体的影响因素，设计了多种结构模型，并通过热风洞试验、FloEFD软件建模和热流体仿真，从材料及结构上系统地提出了优化途径和改善办法并进行了验证，尤其是分析了双余度传感器的响应一致性误差并提出改善方法。研究结果为同类传感器的设计提供了参考和借鉴。     

Probabilistic seismic damage assessment of reinforced concrete buildings considering directionality effects

Most of buildings and structures are usually projected according to two main axes. However, the geographical position of these buildings varies randomly. Such random distributions of the azimuthal positions of structures, in most of the cities, generally, are not accounted for when assessing their seismic risk; certainly, the direction of the seismic loads is another highly random variable. Moreover, an additional important source of uncertainty is related to the structural response, mainly due to the random character of the mechanical properties. There is a consensus that uncertainties must be considered for adequately assessing the seismic risk of structures, but these directionality effects have not been deeply explored so far. In this article, the influence of the high uncertainty involved in these input variables on the expected seismic damage is analysed. Thus, an actual earthquake, which affected the southern part of Spain, is studied. Notably, damages on a group of affected buildings, located close to the epicentre, are analysed and discussed in detail. The results show that the influence of the random azimuthal position of structures is an important source of uncertainty and that it should be taken into account when estimating the expected seismic risk in urban areas.     

高温气冷堆舱室抗商用飞机撞击的耦合数值分析

本文建立了大型商用飞机撞击典型高温气冷堆核电站反应堆舱室的非线性有限元模型，计算中混凝土舱室直接采用工程用钢筋混凝土的损伤塑性本构模型，飞机结构采用Johnson-Cook本构模型。对飞机高速撞击高温气冷堆核电站反应堆舱室非线性撞击过程进行模拟计算，得出正面和侧面撞击条件下的撞击载荷曲线、撞击位移云图、反应堆舱室混凝土破坏情况等结果。评估表明，反应堆舱室结构在撞击条件下的整体损伤微小，可为保护内部关键设备提供重要的屏障功能。     

两池火耦合作用下柴油拱顶罐热响应的数值模拟

化工园区多池火事故是典型的高后果低概率事件。鉴于目前两池火辐射模型存在一定局限性，本文采用数值模拟方法，以3个直线排布的5000m³柴油拱顶罐为研究场景，从热释放速率、火焰形态、热辐射强度三方面分析两池火燃烧特性，并与单池火场景对比，考虑储罐间距这一影响因素，进一步研究目标储罐热响应。结果表明：采用GB 50160—2008（2018年版）规定的防火间距，两燃烧罐产生的池火会发生耦合作用，并得出目标储罐受到的热辐射强度分布，最高热辐射达17.04kW/m²；两池火作用下目标储罐的温度、Mises应力与失效时间分别为644℃、356MPa、936s，单池火为488℃、280MPa、2880s，目标储罐在两池火作用下的变形也比单池火更为严重；随着储罐间距增加，目标储罐的温度与Mises应力逐渐减小，失效时间逐渐增加，当储罐间距为标准防火间距的2.5倍（20m）时，失效时间为2800s，与单池火作用产生的失效时间2880s较为接近。本研究可为优化储罐防火间距及区域韧性提升提供理论指导。     

[成形过程仿真优化与集成计算材料工程]限定加热管布局的快速热循环注塑成形模具电加热系统优化

针对管道布局、最大允许能耗给定条件下快速热循环注塑成形（RHCM）注塑模具型腔表面快速均匀加热的问题，提出以单根加热棒热流密度为设计变量，以模具型腔表面升温效率和温度分布均匀性为目标，结合有限元模拟、响应面设计以及多目标粒子群优化技术来优化RHCM模具电加热系统。与优化前相比，加热系统优化后，模具型腔表面最大温差降低63.4%，加热系统总能耗降低9%。对比了不同注塑成形工艺条件下成形的平板塑件表面质量，结果表明，相对传统注塑成形（CIM）工艺，RHCM工艺将制品表面粗糙度Ra从320 nm降低到118 nm，并有效抑制了制品表面熔接痕、缩痕等缺陷；发现制品表面粗糙度与型腔表面对应点温度成负相关，说明优化后的型腔表面温度分布更有利于提升制品表面质量。